Addition Polymerisation Questions

Addition Polymers

Polymers Worksheet
1. Draw the following polymers:
a) Poly(tetrafluoroethene)
Answer Poly(tetrafluoroethene)
b) Poly(chloroethene)
Answer Poly(chloroethene)
c) Poly(but-2-ene)
Answer Poly(but-2-ene)
d) Poly(phenylethene)
Answer Poly(phenylethene)
2. Draw an equation to represent the formation of the following from their monomers:
a) Poly(propene)
Answer Formation of Poly(propene)
b) Poly(ethenol)
Answer Formation of Poly(ethenol)
Teacher Note: Ethenol is an unstable tautomer of ethanal and does not exist in stable form to polymerise directly. Industrially, Poly(ethenol) is produced by the hydrolysis of poly(ethenyl ethanoate).
3. PVC is the common name for a common polymer.
a) State the IUPAC name of the polymer PVC.
Answer

Poly(chloroethene)

b) Draw an equation to represent the formation of PVC from its monomer.
Answer Formation of PVC
c) State the purpose of a plasticiser in PVC.
Answer

It makes the polymer more flexible.

The plasticiser molecules sit between the polymer chains, pushing them apart. This weakens the intermolecular forces between chains, allowing them to slide over each other more easily.

4. Draw a section of polymer three repeat units long for the following polymers:
a) Poly(propenoic acid)
Answer Poly(propenoic acid)
b) Poly(pent-2-enoic acid)
Answer Poly(pent-2-enoic acid)
5. The following polymers are made up of a mixture of two addition monomers. For each one, draw the structure of the two monomers.
Polymer 1
Answer Monomers for Polymer 1
Polymer 2
Answer Monomers for Polymer 2
Note: The monomers do not have to be alternating in the polymer chain.