Geometric Isomerism Questions

Geometic Isomerim

Intro to Organic Worksheet

Definitions & Explanations

1. Define the term stereoisomerism.

It is where molecules have the same molecular formula and sequence of bonded atoms, but differ in the three-dimensional orientations of their atoms in space.

2. Define the term geometric isomerism.

Geometric isomerism is a type of stereoisomerism around a carbon-carbon double bond.

3. Explain why some alkenes display geometric isomerism.

The carbon-carbon double bond cannot rotate, unlike a carbon-carbon single bond. This means that groups always remain on the ‘side’ that they start and cannot swap sides.

4. Naming Stereoisomers

Name the following molecules, including whether they are E or Z forms of the isomer.
a) Molecule A

E-Pent-2-ene

b) Molecule B

Z-Pent-2-ene

c) Molecule C

E-4,4-dimethyl-Pent-2-ene

d) Molecule D

Z-3-bromo-4-methylpent-2-ene

e) Molecule E

E-1-Bromo-1,2-dichloropent-1-ene

f) Molecule F

Z-2-Butyl-3-methylpent-2-en-1-ol

g) Molecule G

Z-But-2-enoic acid

h) Molecule H

E-3-methylbut-2-ene nitrile

i) Molecule I

E-aminoprop-1-ene